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Presentation on the topic "starch". Presentation for the research work "mysterious starch and its significance" A) in nature


LESSON TOPIC: POLYSACCHARIDES. STARCH AND CELLULOSE

Lesson objectives:

View in comparison

  • structure
  • properties
  • application
  • significance in the nature of starch and cellulose

STARCH and CELLULOSE

Chemical formula

(WITH 6 N 10 ABOUT 5 ) n



CELLULOSE. BEING IN NATURE

Cotton, flax, hemp fibers - almost pure cellulose

Wood contains 50% cellulose

Straw contains 30% cellulose


The structure of starch (C 6 N 10 ABOUT 5 ) n ( n= 200 - 1000)

  • starch macromolecules consist of residues of cyclic α-glucose molecules

STRUCTURE OF CELLULOSE (C 6 H 10 O 5 ) n

(n = 400,000 to 2 million )

Cellulose macromolecules consist of β-glucose residues


SHAPE OF STARCH MOLECULE

Amylose (10-20%) has a linear structure

Amylopectin (80-90%) forms a branched structure

SHAPE OF CELLULOSE MOLECULE

Cellulose has a linear structure


Chemical properties of starch

Starch hydrolysis

  • Starch is easily hydrolyzed:

Stepwise enzymatic hydrolysis of starch.

Starch dextrins maltose glucose

N 2 S ABOUT 4

(WITH 6 N 10 ABOUT 5 )n

+ nH 2 O

nC 6 H 12 O 6

N 2 ABOUT

N 2 ABOUT

N 2 ABOUT


Chemical properties of cellulose

Hydrolysis of cellulose

  • Cellulose (fiber), unlike starch, is difficult to hydrolyze
  • At hydrolysis plants, wood waste (chips, sawdust) is processed into glucose and then into alcohol

N 2 S ABOUT 4

(WITH 6 N 10 ABOUT 5 )n

+ nH 2 O

nC 6 H 12 O 6

(WITH 6 N 10 ABOUT 5 )n

WITH 6 N 12 ABOUT 6

WITH 2 N 5 HE


FORMATION OF CELLULOSE ESTERS

Trinitrocellulose –

explosive pyroxylin

cellulose

Cellulose triacetate

cellulose


  • Trinitrocellulose (pyroxylin) is used as an explosive and in the production of smokeless gunpowder.
  • Dinitrocellulose (colloxylin) is used to produce collodion (to create scars and scars)

Man-made fibers cellulose based



PHOTOSYNTHESIS

6СО 2 + 6H 2 O C 6 N 12 ABOUT 6 + 6O 2

light




Consolidation of knowledge

1. Choose the correct statements:

1. Disaccharides include starch and cellulose.

2. Starch and cellulose have the same molecular formula.

3. Cellulose has a branched molecular structure.

4. Starch swells in hot water.

5. Cellulose dissolves in organic solvents.

6. The hydrolysis reaction is characteristic only of starch.

7. The hydrolysis of cellulose produces glucose molecules.

8. A qualitative reaction for determining starch in natural objects is the iodine reagent

9. Cellulose is used to produce artificial silk.



Write down your homework

§ 13.8.

Home Study .

Enzymatic hydrolysis of starch .

Human saliva contains the digestive enzyme amylase. Under the action of amylase (ptialin), starch hydrolysis occurs.

Chew well (at least 10 minutes) a small piece of black bread.

Do taste sensations change?

How can this be explained?

Place it in a porcelain cup. Add a drop of iodine solution to it.

What are you observing? What can be concluded?

Tell us about the results of your experiments.



PROPERTIES

STARCH

1.Being in nature

2. Chemical formula

CELLULOSE

3. The molecule consists of residues...


PROPERTIES

STARCH

4. Structural link formula

5.Number of structural links

CELLULOSE

6.Molecular weight

7. Molecule shape


STARCH

8. Physical properties

CELLULOSE


STARCH

9. Chemical properties

CELLULOSE

Hydrolysis reaction

Hydrolysis reaction:


Determination of starch in food


STARCH

8.Receipt

A) in nature

B) in industry

Application

Slide 1

Slide 2

Starch consists of 2 polysaccharides - amylose and amylopectin, formed by glucose residues. It has been experimentally proven that the chemical formula of starch is (C6H10O5)n. It has been established that starch consists not only of linear molecules, but also of molecules with a branched structure. This explains the granular structure of starch. Accumulates in the form of grains, mainly in the cells of seeds, bulbs, tubers, as well as in leaves and stems. Starch is a white powder, insoluble in cold water. In hot water it swells and forms a paste. The structure of starch.

Slide 3

Physical Properties Tasteless, amorphous white powder, insoluble in cold water; in hot water it swells (dissolves), forming a colloidal solution - a paste. Under a microscope it can be seen that it is a granular powder; When you squeeze starch powder in your hand, it produces a characteristic “crunch” caused by the friction of the particles.

Slide 4

chemical properties It swells in hot water, in water and with the addition of acid (H2SO4, diluted, etc.) as a catalyst, it gradually hydrolyzes with a decrease in molecular weight, down to glucose. Forms a colloidal solution (starch paste); with iodine solution gives a blue color. Starch molecules are heterogeneous in size. Starch is a mixture of linear and branched macromolecules. Under the action of enzymes or heating with acids, it undergoes hydrolysis. Equation: (C6H10O5)n + nH2O-H2SO4→ nC6H12O6. Qualitative reactions: Starch, unlike glucose, does not give a silver mirror reaction. Like sucrose, it does not reduce copper(II) hydroxide. Interaction with iodine (blue color).

Slide 5

Nutritional value In the gastrointestinal tract of humans and animals, starch is hydrolyzed and converted into glucose, which is absorbed by the body. Starch, as a food additive, is used to thicken many foods, prepare jelly, dressings and sauces.

Slide 6

Biological properties Starch, being one of the products of photosynthesis, is widespread in nature. For plants, it is a supply of nutrients and is found mainly in fruits, seeds and tubers. The grains of cereal plants are the richest in starch: rice (up to 86%), wheat (up to 75%), corn (up to 72%), and potato tubers (up to 24%).

Slide 7

For the human body, starch, along with sucrose, serves as the main supplier of carbohydrates - one of the most important components of food. Under the action of enzymes, starch is hydrolyzed to glucose, which is oxidized in cells to carbon dioxide and water, releasing energy necessary for the functioning of a living organism.

Slide 8

Modification of starch In industry, the conversion of starch into glucose (saccharification process) occurs by boiling it for several hours with dilute sulfuric acid (the catalytic effect of sulfuric acid on the saccharification of starch was discovered in 1811 by K. S. Kirchhoff). To remove sulfuric acid from the resulting solution, chalk is added to it, producing insoluble calcium sulfate from sulfuric acid. The latter is filtered off and the substance is evaporated. The result is a thick sweet mass - starch syrup, which contains, in addition to glucose, a significant amount of other starch hydrolysis products. Molasses is used for the preparation of confectionery products and for a variety of technical purposes. If you need to get pure glucose, then boiling the starch takes longer than it is more completely converted into glucose. The solution obtained after neutralization and filtration is concentrated until glucose crystals begin to fall out of it. Also, currently, starch hydrolysis is carried out enzymatically, using alpha-amylase to produce dextrins of various lengths, and glucoamylase for their further hydrolysis to produce glucose.

Slide 9

When dry starch is heated to 200-250°C, its partial decomposition occurs and a mixture of polysaccharides (dextrin and others) that are less complex than starch is obtained. The physical change produces starch with a high moisture-holding capacity, which in turn gives the final product the desired consistency. Modified starch has nothing to do with genetically modified organisms, since it is not changed at the genetic level. Modified starch

Slide 10

Application of starch. Starch is the main part of the most important food products: flour (75 - 80%), potatoes (25%), sago, etc. Energy value is about 16.8 kJ/g. It is a valuable nutritious product. To facilitate its absorption, starch-containing foods are exposed to high temperatures, that is, potatoes are boiled, bread is baked. Under these conditions, partial hydrolysis of starch occurs and dextrins, soluble in water, are formed. Dextrins in the digestive tract undergo further hydrolysis to glucose, which is absorbed by the body. Excess glucose is converted into glycogen (animal starch). The composition of glycogen is the same as that of starch - (C6H10O5)n, but its molecules are more branched. The liver contains especially a lot of glycogen (up to 10%). In the body, glycogen is a reserve substance that is converted into glucose as it is consumed in cells. In industry, starch is converted into molasses and glucose by hydrolysis. To do this, it is heated with dilute sulfuric acid, the excess of which is then neutralized with chalk.

Slide 11

The resulting precipitate of calcium sulfate is filtered off, the solution is evaporated and glucose is isolated. If starch hydrolysis is not completed, a mixture of dextrins and glucose is formed - molasses, which is used in the confectionery industry. Dextrins obtained from starch are used as glue to thicken paints when applying designs to fabric. Starch is used for starching linen. Under a hot iron, starch is partially hydrolyzed and converted into dextrins. The latter form a dense film on the fabric, which adds shine to the fabric and protects it from soiling. Starch and its derivatives are also used in the production of paper, textiles, foundries and other industries, as well as in the pharmaceutical industry. Water + Starch + Subwoofer The combination of “starch + water” is a so-called “non-Newtonian fluid”, i.e. a liquid that is not affected by Newton's laws. The property of such a mass is ductility. it can behave both as a liquid and as a powder.

Research student 2 "A" class MBOU "OOSH" No. 7 Bondarenko Danila

Mysterious starch and its significance for humans

Head: Belozerova Natalya Nikolaevna


Goal of the work:

  • Find out what effect foods containing starch have on our health.

2. Determine what foods adults and children like to eat: with or without starch.


Z adachi:

1. Study information about starch.

2. Study methods for detecting starch in food.

3. Conduct a survey among adults and children about their favorite foods.

4. Conduct an experiment to determine the presence of starch in food products, based on survey data.

5. Analyze the survey results.

6. Study the areas of application of starch.

Object of study: starch

Subject of study: Food

Research methods: literature study, experiments, surveys, observations


HYPOTHESIS.

If we study starch, we will learn about the benefits or harms of starch and this can allow us to create the right diet.


What is starch?

STARCH - the main reserve carbohydrate of plants is formed in their cells and accumulates mainly in seeds, bulbs and tubers, as well as in leaves and stems.

Properties of starch.

  • Tasteless white powder, insoluble in cold water.
  • IN in his hand he makes a “creaking” noise caused by the friction of particles.
  • It swells (dissolves) in hot water, forming a viscous solution - a paste;
  • WITH solution of iodine forms a compound that has blue color.

The role of starch in human nutrition .

Starch is a carbohydrate, one of the main sources of energy for humans.

Conclusions:

1. Starch is beneficial because it quickly replenishes a person’s energy.

But its excess can cause harm - overweight, obesity, obesity.

2. Nutrition should be balanced


EXPERIMENTS

To study properties starch I chose potato starch.

Hypothesis: starch creaks

Experience 1: I poured starch into a cup. I rubbed it between my fingers: indeed, a slight creak was heard

Hypothesis: starch does not dissolve in cold water, turns into a glue-like mass

Experience 2: He poured water into a glass and mixed water with starch. Starch did not dissolve in water. While stirring, a viscous mixture formed at the bottom of the glass. On it felt sticky to the touch.


starch reacts with iodine to give a blue or purple tint.

Experience 3: For this I took: a napkin, iodine, dry starch, starch mixed with water.

Dropped a few drops of iodine onto a napkin, into dry starch and starch mixed with water

  • Iodine on a brown napkin.
  • When reacting with dry starch, iodine turns dark purple.
  • If iodine is added to starch mixed with water, we see that it turns dark blue.

Conclusion: All hypotheses about the properties of starch were confirmed


Survey .

We conducted a survey among children and adults about what foods they like most.

Adults were also asked the question: “What do you know about starch?”

Participated in the survey: students of grade 2 “A” of our school – 30 people, primary school teachers, my grandmother and colleagues from my mother’s work – 15 people.

We received the following survey results:


Five most popular food products .

Children

1 . apple 11 people

2 . banana 11 people

3 . tangerine 6 people

4 . chicken/meat 5 people

5 . milk 4 people

Adults

1 . potatoes 6 people

2 . fish 4 people

3 . meat 4 people

4 . yogurt 3 people

5 . fruits 3 people

The following products were selected for testing for the presence of starch:

7 . fish

8 . yogurt

1 . apple

2 . banana

3 . mandarin

4 . chicken

5 . milk

6 . potato

9 . cabbage

10 . tomato

11 . baked goods (bread, cookies)

Cabbage, tomato and pastries were selected additionally from the survey, they scored equal votes with fruit and yogurt


The products were divided into groups:

  • Vegetable origin
  • Animal origin
  • Mixed

Animal products

Mixed group:

P Origin:

Vegetable products

origin:

11 . bread

12 . cookie

1 . apple

2 . banana

3 . mandarin

4 . potato

5 . cabbage

6 . tomato

7 . chicken

8 . milk

9 . Yogurt

10 . fish


Experience 4 : checked the presence of starch in food products of plant origin

Each product was placed in a separate cup and iodine was dropped onto it.

Overripe banana

Mandarin

Unripe banana

Apple

Potato

Tomato

Cabbage


We got the following results:

No starch :

  • . in an apple
  • . in an overripe banana
  • . in mandarin
  • . in cabbage
  • . in tomato

Starch is:

1. in an unripe banana

2. in potatoes

Conclusions:

  • Not all plants contain starch
  • As some foods ripen, starch may disappear from them.

We turned to the Internet, the Medical Information Network site, and learned that as bananas ripen, the starch turns into sugar. Therefore, ripe bananas are sweeter.


Experience 5: checked the presence of starch in foods of animal origin

Each product was placed in a separate cup and iodine was dropped onto it.

Milk

Yogurt

Chicken

Conclusions: animal products do not contain starch

Fish


Experience 6: Checked for starch in mixed foods

Each product was placed in a separate cup and iodine was dropped onto it.

Cookie

Bread

The composition of cookies and bread includes products of plant origin: wheat (wheat flour) and animal products - butter or margarine.

Wheat contains starch, and margarine or butter contains animal fat

Conclusion: in mixed products, starch does not disappear anywhere.


Analysis of survey results .

When surveying children, it became clear that the majority like: apples and bananas.

We know that most children love ripe bananas. This means that the starch content in them is minimal. Other products also do not contain starch

When interviewing adults It became clear that most people love potatoes. In second and third place are fish and meat.

From experience, potatoes contain a lot of starch. Fish and meat and other products do not contain starch.

Conclusions:

1. Most students in grade 2 “A” prefer foods that do not contain starch.

2. Most adults prefer mixed foods.


Other uses of starch

From the adult survey I also learned:

1. Starch can be useful in everyday life: it used to be used to treat shirt collars. This made them appear whiter. And since starch hardens when it dries, the collars held the shape they were given. Napkins and tablecloths were starched for this purpose.

2. Starch was used by artists: previously, canvases for painting were treated with starch so that paints would not leak through them.

3. Nowadays, starch is used in the manufacture of: tablets, ointments and powders, and also

in the production of paper, cardboard, paints, glue. And I was surprised when I learned that starch is used in the manufacture of sausages and sausages.


Conclusion .

1. Starch can bring both benefit and harm to humans.

2. It is important to eat right, consume foods that contain starch in moderation, but you cannot avoid them, a person needs them.

3. I found out that students in our class prefer foods without starch. And adults love mixed foods.

Adults need to monitor their children’s nutrition so that they replenish energy on time and sufficiently. Since without adult supervision, most of the students in our class will eat only fruits on their own, and this is not enough for their healthy development .

Starch can be found in food products: pasta, vermicelli, bread, pancakes, flour products, jelly, porridge

And also to grow properly and keep your weight normal – you need to play sports!


Thank you for your attention.

Be healthy!


Starch in its chemical composition and structure belongs to carbohydrates. Widely distributed in nature. It is found in large quantities in cereal grains, vegetable tubers, food products - bread, pasta and flour confectionery, food concentrates, etc.


Starch makes up the bulk of carbohydrates consumed by humans. It is easily absorbed by the body and has a high nutritional value as an energy substance. The most important property of starch is its ability to swell and gelatinize, due to which it has high consumer value and is widely used in various sectors of the food industry, medicine, textile, paper, printing industries, for production dextrins, and also as a consumer product.


Types potato - obtained from potato tubers, forms a viscous transparent paste; corn - has a low viscosity, an opaque paste of milky white color, after cooking it retains the specific odors and taste of corn grain; wheat - has low viscosity, more transparent compared to corn; amylopectin - obtained from waxy corn, a paste of good viscosity, with good moisture resistance, gives a characteristic red-brown color with iodine solution;


high-amylose types - obtained from high-amylose varieties of corn, used in the form of transparent films and edible food casings in the food industry; modified - with directionally changed properties, comes in the following varieties: swelling starch - obtained by drying the paste on special dryers and grinding the film into powder, the particles of which swell when wetted with water and increase in volume;


types of oxidized starch - obtained by oxidation with various oxidizing agents; depending on the degree of oxidation, starch with different viscosity and gelling ability can be obtained; gelling starch - is one of the types of oxidized starch; is obtained by treating (CMnO) a starch suspension in an acidic environment. It is used as a gelling agent instead of agar and agaroid: potato gelling starch grades A and B - in the confectionery industry, potato and corn gelling starch - in the refrigeration industry.


GOST 7699-78. 7697-66 The quality of starch (GOST 7699-78. 7697-66) is assessed according to the indicators given in table. 91 and 92. Starch for food purposes must be free of foreign tastes and odors. Admixtures of other types of starch and heavy metal salts are not allowed. When sifting 100 g of starch through a silk sieve No. 55, no sand should remain. Grade 2 starch is intended only for technical purposes and industrial processing.


Starch defects occur mainly when production technology or storage conditions are violated. These include the presence of mechanical and foreign impurities, the smell and taste of a spoiled product (fermentation), a crunch when chewing from mineral impurities (sand), the gray color of starch and its high humidity. Starch with such defects is used for technical purposes.


starch is packaged in double fabric or paper bags: the inner bag is fabric, multilayer paper or film liner (GOST 19360-74); outer bag (GOST 8516-67, 19317-73 or GOST 18225-72) - new or used, not lower than category III. Potato starch is packaged in bags with a net weight of no more than 50 kg, corn starch - 25, 50, 60, and for industrial processing - 70 kg. Bags filled with starch are sewn up by machine or by hand or tied with twine.


Starch can be packaged in small containers made of paper, polyethylene, PC-2 film and other polymeric materials approved by the USSR Ministry of Health, weighing from 250 to 1000 g. Packs and packages are placed in wooden, plywood and corrugated cardboard boxes with a net weight of no more 30 kg. Marking is applied in accordance with GOST 14192-77 with the warning notice “Afraid of dampness”.


Storage Store starch in packaged form in well-ventilated warehouses that are free of foreign odors and not infested with flour pests. It is not allowed to store starch together with products that have a specific odor. Bags and boxes must be placed on racks, covered with tarpaulin or other materials so that the bottom row of the stack is closed on the sides. The most important condition for proper storage of starch is maintaining a relative air humidity in warehouses of no more than 75%. The guaranteed shelf life of potato starch is 2 years from the date of production.

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Starch

Variety of substances

The world

Educational and training complex "School of Russia"


Goal of the work

Get to know

properties of starch.

Find out how it is obtained and where it is used.

Add the starch sample to the substance collection.


  • Chemical starch formula
  • A model of this molecule can be made

Properties of starch

Free-flowing white powder, tasteless and odorless, creaks when rubbed.

Starch does not dissolve at all in cold water, and after a while it “sits” to the bottom and the solution becomes almost transparent;

In warm water it forms a milky liquid, and after a while it “sits” to the bottom and the solution becomes transparent.

Starch in hot water only swells, but does not dissolve. The result was a colorless viscous mass, sticky to the touch. From the literature I learned that this solution is called a paste.


Being in nature

In corn and wheat 70 percent

Rice contains 80 percent.

In potato tubers - 25 percent.


  • Starch is most often obtained from potatoes in factories. To do this, the potatoes are crushed, washed with water and pumped into large vessels where settling occurs. The resulting starch is washed again with water, settled and dried in a stream of warm air.

Food industry

Paper industry

Application

Medicine

Starch is the basis for the production of glue


Using starch at home

Starch shirts - soak in starch solution

Preparing jelly

Starch paste,

which glues paper so well


conclusions

  • starch is a white, tasteless substance;
  • insoluble in cold water, swells in hot water, forming a paste;
  • creaks when friction occurs;
  • has physical and chemical properties;
  • occurs in nature;
  • it is obtained in factories mainly from potatoes
  • a person needs to eat and maintain health;
  • used in medicine,

cosmetics and other

industry


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